Claudio SANTO

Position
Technical Administrative Staff
Telephone
041 234 8570 / 041 234 8930
E-mail
santoc@unive.it
Website
www.unive.it/people/santoc (personal record)
Office
Department of Molecular Sciences and Nanosystems
Website: https://www.unive.it/dep.dsmn
Where: Campus scientifico via Torino
Room: office 608 (Alfa building, 6th floor) / research lab 8 (Beta building, 3rd floor)
Sicurezza
Addetto Squadre di Emergenza
Preposto di Laboratorio
Referente per le Emergenze di Sede

Publications

Year Type Publication
Year Type Publication
2024 Journal Article Tonon, Giovanni; Mauceri, Matteo; Cavarzerani, Enrico; Piccolo, Rachele; Santo, Claudio; Demitri, Nicola; Orian, Laura; Nogara, Pablo A.; Rocha, João Batista T.; Canzonieri, Vincenzo; Rizzolio, Flavio; Visentin, Fabiano; Scattolin, Thomas Unveiling the promising anticancer activity of palladium(ii)–aryl complexes bearing diphosphine ligands: a structure–activity relationship analysis in DALTON TRANSACTIONS, vol. 53, pp. 8463-8477 (ISSN 1477-9226)
DOI - ARCA card: 10278/5060662
2020 Journal Article Scattolin T.; Santo C.; Demitri N.; Canovese L.; Visentin F. Chemoselective oxidative addition of vinyl sulfones mediated by palladium complexes bearing picolyl-N-heterocyclic carbene ligands in DALTON TRANSACTIONS, vol. 49, pp. 5684-5694 (ISSN 1477-9226)
DOI - ARCA card: 10278/3728812
2020 Journal Article Scattolin T.; Canovese L.; Santo C.; Visentin F. Measuring the Olefin-to-Pd(0) Bond Strength: A Kinetic Study Involving Olefin Exchange Reactions on Palladium(0) Complexes Bearing Isocyanide Ligands in HELVETICA CHIMICA ACTA, vol. 103 (ISSN 0018-019X)
DOI - ARCA card: 10278/3736981
2019 Journal Article Scattolin, Thomas; Moro, Giulia; Rizzolio, Flavio; Santo, Claudio; Moretto, Ligia Maria; Visentin., Fabiano Improved Synthesis, Anticancer Activity and Electrochemical Characterization of Unusual Zwitterionic Palladium Compounds with a Ten‐Term Coordinative Ring in CHEMISTRYSELECT, vol. 4, pp. 10911-10919 (ISSN 2365-6549)
DOI - ARCA card: 10278/3719138
2019 Journal Article Scattolin T.; Canovese L.; Demitri N.; Santo C.; Visentin F. The importance of the electronic and steric features of the ancillary ligands on the rate of cis–trans isomerization of olefins coordinated to palladium(0) centre. A study involving (Z)-1,2-ditosylethene as olefin model in POLYHEDRON, vol. 173, pp. 114144 (ISSN 0277-5387)
DOI - URL correlato - ARCA card: 10278/3720371
2019 Journal Article Giacomo Berton, Tommaso Lorenzetto, Giuseppe Borsato, Paolo Sgarbossa, Claudio Santo, Fabiano Visentin, Fabrizio Fabris, Alessandro Scarso Triphenylene based metal-pyridine cages in TETRAHEDRON LETTERS, vol. 60, pp. 151202 (ISSN 0040-4039)
DOI - ARCA card: 10278/3719246
2018 Journal Article Scattolin, T.; Canovese, L.*; Visentin, F.; Santo, C.; Demitri, N. Synthesis and characterization of novel olefin complexes of palladium(0) with chelating bis(N-heterocyclic carbenes) as spectator ligands in POLYHEDRON, vol. 154, pp. 382-389 (ISSN 0277-5387)
DOI - URL correlato - ARCA card: 10278/3703203
2018 Journal Article Scattolin, Thomas; Canovese, Luciano; Demitri, Nicola; Gambari, Roberto; Lampronti, Ilaria; Santo, Claudio; Visentin, Fabiano; Rizzolio, Flavio; Caligiuri, Isabella Synthesis of new allyl palladium complexes bearing purine-based NHC ligands with antiproliferative and proapoptotic activity on human ovarian cancer cell lines in DALTON TRANSACTIONS, vol. 47, pp. 13616-13630 (ISSN 1477-9226)
DOI - ARCA card: 10278/3704674
2018 Journal Article Canovese, L.*; Visentin, F.; Scattolin, T.; Santo, C.; Bertolasi, V. Synthesis of novel olefin complexes of palladium(0) bearing monodentate NHC, phosphine and isocyanide spectator ligands in POLYHEDRON, vol. 144, pp. 131-143 (ISSN 0277-5387)
DOI - URL correlato - ARCA card: 10278/3697632
2017 Journal Article Scattolin, Thomas; Visentin, Fabiano; Santo, Claudio; Bertolasi, Valerio; Canovese, Luciano Isocyanide insertion across the Pd–C bond of allenyl and propargyl palladium complexes bearing phosphoquinoline as a spectator ligand. Synthesis of a palladium complex bearing a coordinated cyclobutenyl fragment in DALTON TRANSACTIONS, vol. 46, pp. 5210-5217 (ISSN 1477-9226)
DOI - ARCA card: 10278/3685855
2017 Journal Article Canovese, Luciano; Scattolin, Thomas; Visentin, Fabiano; Santo, Claudio Reactions of palladium(0) olefin complexes stabilized by some different hetero- and homo-ditopic spectator ligands with propargyl halides in JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 834, pp. 10-21 (ISSN 0022-328X)
DOI - URL correlato - ARCA card: 10278/3685852
2017 Journal Article Visentin, Fabiano; Santo, Claudio; Scattolin, Thomas; Demitri, Nicola; Canovese, Luciano Reactivity of N-heterocyclic carbene-pyridine palladacyclopentadiene complexes toward halogen addition. the unpredictable course of the reaction in DALTON TRANSACTIONS, vol. 46, pp. 10399-10407 (ISSN 1477-9226)
DOI - URL correlato - ARCA card: 10278/3690764
2017 Journal Article Canovese, Luciano; Visentin, Fabiano; Scattolin, Thomas; Santo, Claudio; Bertolasi, Valerio Synthesis and reactivity toward olefin exchange and oxidative addition of some platinum(0) olefin complexes with thioquinolines as spectator ligands in POLYHEDRON, vol. 129, pp. 229-239 (ISSN 0277-5387)
DOI - ARCA card: 10278/3685856
2016 Journal Article Canovese, L.; Visentin, F.; Scattolin, T.; Santo, C.; Bertolasi, V. Addition of halogens and interhalogens on palladacyclopentadienyl complexes stabilized by pyridyl-thioether N-S spectator ligands in JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 808, pp. 48-56 (ISSN 0022-328X)
DOI - ARCA card: 10278/3673315
2016 Journal Article Canovese, L; Visentin, F.; Scattolin, T.; Santo, C.; Bertolasi, V. Synthesis, characterization and a reactivity study of some allyl palladium complexes bearing bidentate hemi-labile carbene or mixed carbene/PPh3 ligands in POLYHEDRON, vol. 119, pp. 377-386 (ISSN 0277-5387)
DOI - URL correlato - ARCA card: 10278/3682103
2016 Journal Article Canovese, L; Visentin, F.; Scattolin, T.; Santo, C.; Bertolasi, V. The addition of halogens and interhalogens on palladacyclopentadienyl complexes bearing quinolyl-thioether as spectator ligands. A kinetic and computational study in POLYHEDRON, vol. 113, pp. 25-34 (ISSN 0277-5387)
DOI - URL correlato - ARCA card: 10278/3673316
2016 Journal Article Scattolin, Thomas; Visentin, Fabiano; Santo, Claudio; Bertolasi, Valerio; Canovese, Luciano The unexpected case of reactions of halogens and interhalogens with halide substituted Pd(II) sigma-butadienyl complexes in DALTON TRANSACTIONS, vol. 45, pp. 11560-11567 (ISSN 1477-9234)
DOI - ARCA card: 10278/3675697
2016 Abstract in Atti di convegno Scattolin, Thomas; Visentin, Fabiano; Canovese, Luciano; Santo, Claudio A simple and alternative way for the methylation of functionalized purine bases , XXXVII Congresso Divisione Chimica Organica, SCI, Convegno: XXXVII Congresso Divisione Chimica Organica
- ARCA card: 10278/3682767
2016 Abstract in Atti di convegno Scattolin, Thomas; Visentin, Fabiano; Canovese, Luciano; Santo, Claudio Computational investigations on the unexpected extrusion of molecular iodine in Pd(II) σ-butadienyl complexes , IV° congresso nazionale di chimica teorica e computazionale, SCI, Convegno: IV° congresso nazionale di chimica teorica e computazionale
- ARCA card: 10278/3682764
2016 Abstract in Atti di convegno Scattolin, Thomas; Visentin, Fabiano; Canovese, Luciano; Santo, Claudio Halogen metathesis in Pd(II) σ-butadienyl complexes , XLIV Congresso Nazionale di Chimica Inorganica, SCI, Convegno: XLIV Congresso Nazionale di Chimica Inorganica
- ARCA card: 10278/3682768
2016 Abstract in Atti di convegno Scattolin, Thomas; Visentin, Fabiano; Canovese, Luciano; Santo, Claudio; Bergamini, Paola; Marvelli, Lorenza; Lampronti, Ilaria; Gambari, Roberto Synthesis, characterization and antiproliferative activity of theophyllinebased Pd(II) allyl complexes , XVI Workshop on PharmacoBioMetallics, CIRCMSB, Convegno: XVI Workshop on PharmacoBioMetallics
- ARCA card: 10278/3682765
2015 Journal Article L. Canovese; F. Visentin; C. Biz; T. Scattolin; C. Santo; V. Bertolasi Oxidative addition of allyl and propargyl halides on palladium(0) complexes bearing bidentate ligands with quinolinic structure in JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 786, pp. 21-30 (ISSN 0022-328X)
DOI - ARCA card: 10278/3656342
2015 Journal Article Luciano Canovese; Fabiano Visentin; Chiara Biz; Thomas Scattolin; Claudio Santo; Valerio Bertolasi Oxidative addition of organic halides on palladium(0) complexes stabilized by dimethylfumarate and quinoline-based N-P or N-S spectator ligands in POLYHEDRON, vol. 102, pp. 94-102 (ISSN 0277-5387)
DOI - ARCA card: 10278/3661666
2015 Journal Article Luciano Canovese; Claudio Santo; Thomas Scattolin; Fabiano Visentin ; Valerio Bertolasi, Synthesis and characterization of palladacyclopentadiene complexes with N-heterocyclic carbene ligands in JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 794, pp. 288-300 (ISSN 0022-328X)
DOI - ARCA card: 10278/3661663
2015 Journal Article Canovese, Luciano; Visentin, Fabiano; Scattolin, Thomas; Santo, Claudio; Bertolasi, Valerio The addition of bromine and iodine to palladacyclopentadienyl complexes bearing bidentate heteroditopic P-N spectator ligands derived from differently substituted quinolinic frames. The unexpected evolution of the reaction in DALTON TRANSACTIONS, vol. 44, pp. 15049-15058 (ISSN 1477-9226)
DOI - ARCA card: 10278/3661665
2014 Journal Article L. Canovese;F. Visentin; C. Santo Attack of molecular iodine to novel palladacyclopentadienyl complexes bearing isocyanides as spectator ligands. A computational and mechanistic study in JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 770, pp. 6-13 (ISSN 0022-328X)
DOI - ARCA card: 10278/41020
2014 Journal Article L. Canovese; F. Visentin; C. Santo; V. Bertolasi Insertion of Isocyanides across the Pd_C Bond of Phosphinoquinoline Allyl Palladium Complexes Bearing η1- and η3-Coordinated Allyl Groups. A Synthetic and Mechanistic Study in ORGANOMETALLICS, vol. 33, pp. 1700-1709 (ISSN 0276-7333)
DOI - ARCA card: 10278/39995
2014 Journal Article L. Canovese;F. Visentin;C. Santo;V. Bertolasi Low valent palladium benzoquinone complexes bearing different spectator ligands. The versatile coordinative capability of benzoquinone in JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 749, pp. 379-386 (ISSN 0022-328X)
DOI - URL correlato - ARCA card: 10278/39768
2014 Journal Article L. Canovese; F. Visentin; C. Santo Reactivity of palladium olefin complexes with heteroditopic NHC–pyridine as spectator ligand toward olefin exchange in INORGANICA CHIMICA ACTA, vol. 421, pp. 326-334 (ISSN 0020-1693)
DOI - ARCA card: 10278/40695
2013 Journal Article L. Canovese; F. Visentin; C. Levi; C. Santo Synthesis of novel heteroditopic carbene–pyridine palladium(II) chloro vinyl complexes. Comparative reactivity of different palladium vinyl derivatives toward transmetalation with alkynyl stannane in INORGANIC CHEMISTRY COMMUNICATIONS, vol. 32, pp. 74-77 (ISSN 1387-7003)
DOI - ARCA card: 10278/38305
2013 Journal Article L. Canovese; F.Visentin; C.Levi; C.Santo; V.Bertolasi Synthesis of novel palladium allyl complexes bearing heteroditiopic NHC-S ligands. Kinetic study on the carbene exchange between bis-carbene palladium allyl complexes in JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 732, pp. 27-39 (ISSN 0022-328X)
DOI - ARCA card: 10278/37448
2013 Journal Article L. Canovese; F. Visentin; C. Levi; C. Santo; V. Bertolasi Transmetalation between Au(I) and Sn(IV) complexes. The reaction mechanism in non-coordinating and coordinating polar solvents. in INORGANICA CHIMICA ACTA, vol. 404, pp. 105-112 (ISSN 0020-1693)
DOI - ARCA card: 10278/38306
2012 Journal Article L. CANOVESE ; F. VISENTIN; C. LEVI; C. SANTO Reactivity of cationic gold(I) carbene complexes toward oxidative addition of bromine in INORGANICA CHIMICA ACTA, vol. 391, pp. 141-149 (ISSN 0020-1693)
DOI - ARCA card: 10278/30789
2012 Journal Article L. Canovese;F. Visentin;C .Levis;C .Santo; V.Bertolasi The interaction between heteroditopic pyridine–nitrogen NHC with novel sulfur NHC ligands in palladium(0) derivatives: Synthesis and structural characterization of a bis-carbene palladium(0) olefin complex and formation in solution of an alkene–alkyne mixed intermediate as a consequence of the ligandshemilability in INORGANICA CHIMICA ACTA, vol. 390, pp. 105-118 (ISSN 0020-1693)
DOI - ARCA card: 10278/31018
2011 Journal Article L. Canovese; F. Visentin; C. Levi; C. Santo;V. Bertolasi Facile synthesis and reactivity study of mixed phosphane-isocyanide Pd(II) and Pd(0) complexes in INORGANICA CHIMICA ACTA, vol. 378, pp. 239-249 (ISSN 0020-1693)
DOI - ARCA card: 10278/26073
2010 Journal Article L. Canovese;F. Visentin; C. Santo;G. Chessa;V. Bertolasi Allyl Amination of Phosphinoquinoline Allyl Complexes of Palladium. Influence of the AllylHapticity on the Reaction Rate and Regiochemistry. in ORGANOMETALLICS, vol. 29, pp. 3027-3038 (ISSN 0276-7333)
DOI - ARCA card: 10278/32158
2010 Journal Article A. SCARSO; COLLADON M; SGARBOSSA P; SANTO C; MICHELIN R.A; STRUKUL G Highly Active and Selective Platinum(II)-Catalyzed Isomerization of Allylbenzenes: Efficient Access to (E)-Anethole and Other Fragrances via Unusual Agostic Intermediates in ORGANOMETALLICS, vol. 29, pp. 1487-1497 (ISSN 0276-7333)
DOI - ARCA card: 10278/3696
2009 Journal Article CANOVESE L.; F. VISENTIN; C. SANTO; C. LEVI Migratory Insertion of Allyl Groups across the Pd−C Bond in Palladium(II) Isocyanide Complexes. The Fundamental Interplay between Temperature and Allyl Hapticity in ORGANOMETALLICS, vol. 28, pp. 6762-6770 (ISSN 0276-7333)
- ARCA card: 10278/32132
2009 Journal Article LUCCHINI V; BORSATO; G; CANOVESE L.; SANTO C; VISENTIN F; ZAMBON A Qualitative and quantitative discrimination of fake and true alkene rotation processes in pd(η2-olefin) complexes. A new bimolecular mechanism in INORGANICA CHIMICA ACTA, vol. 362, pp. 2715-2721 (ISSN 0020-1693)
DOI - ARCA card: 10278/21629
2009 Journal Article CANOVESE L.; F. VISENTIN; G. CHESSA; C. SANTO; A. DOLMELLA Substitution reactions between bis-chelate ligands in palladium(II) alkenyl complexes: an unusual way to form unstable trans-P complexes. A study on the isomerization mechanism in DALTON TRANSACTIONS, vol. 2009, pp. 9475-9485 (ISSN 1477-9226)
- ARCA card: 10278/22588
2009 Journal Article CANOVESE L.; VISENTIN F; SANTO C; DOLMELLA A The role of ancillary ligands and of electron poor alkenes and alkynes in stabilizing Pd(0) derivatives: A comparative study in JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 694, pp. 411-419 (ISSN 0022-328X)
DOI - ARCA card: 10278/19065
2008 Journal Article CANOVESE L.; SANTO C; VISENTIN F Pd(0)-catalyzed cis-trans Alkene Isomerization in ORGANOMETALLICS, vol. 27, pp. 3577-3581 (ISSN 0276-7333)
- ARCA card: 10278/29840
2008 Journal Article CANOVESE L.; VISENTIN F; LEVI C; SANTO C Transmetalation Reactions. The Surprising Role of the Stabilizing Olefin in Determining the Overall Reaction Rate in JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 693, pp. 3324-3330 (ISSN 0022-328X)
DOI - ARCA card: 10278/17507
2008 Article in Conference Proceedings CANOVESE L; SANTO C; CHESSA G.; VISENTIN F A simple and definitive proof of cis-trans isomerization of a Pd(0)-coordinated olefin without the assistance of an external promoter , ICOMC 2008 Rennes, pp. P794, Convegno: XXIII International Conference on Organometallic Chemistry - Rennes, 13-18 luglio 2008
- ARCA card: 10278/20266
2007 Journal Article CANOVESE L; VISENTIN F.; SANTO C; LEVI C; DOLMELLA A Insertion of Isocyanides across the Pd-C Bond in Alkyl or Aryl Palladium(II) Complexes Bearing Mixed Nitrogen-Sulfur and Nitrogen-Phosphorus Ancillary Ligands. The Mechanism of Reaction in ORGANOMETALLICS, vol. 26, pp. 5590-5601 (ISSN 0276-7333)
- ARCA card: 10278/30027
2007 Journal Article CANOVESE L; VISENTIN F.; SANTO C The formation of a metallacycloheptadienyl intermediate in the reaction of palladacyclopentadienyl derivatives with tetracyanoethylene in JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 692, pp. 4187-4192 (ISSN 0022-328X)
DOI - ARCA card: 10278/15176
2007 Journal Article CANOVESE L.; VISENTIN F.; CHESSA G.; UGUAGLIATI P; SANTO C; MAINI L The synthesis of palladacyclopentadienyl derivatives from rigid bis-alkynes and their use as precursors in the synthesis of fluoroanthene-like cycles under mild conditions. A reactivity investigation in JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 692, pp. 2342-2345 (ISSN 0022-328X)
DOI - ARCA card: 10278/15406
2006 Journal Article CANOVESE L; VISENTIN F; CHESSA G.; SANTO C; LEVI C; UGUAGLIATI P Oxidative coupling of activated alkynes with palladium(0) olefin complexes: Side production of the highly symmetric hexamethyl mellitate species under mild conditions at low alkyne/complex molar ratios in INORGANIC CHEMISTRY COMMUNICATIONS, vol. 9, pp. 388-390 (ISSN 1387-7003)
DOI - ARCA card: 10278/12363
2005 Journal Article CANOVESE L.; VISENTIN F.; CHESSA G.; UGUAGLIATI P.; SANTO C.; DOLMELLA A. Insertion of Substituted Alkynes into the Pd-C Bond of Methyl and Vinyl Palladium(II) Complexes Bearing Pyridylthioethers as Ancillary Ligands. The Influence of Ligand Substituents at Pyridine and Sulphur on the Rate of Insertion in ORGANOMETALLICS, vol. 24, pp. 3297-3308 (ISSN 0276-7333)
DOI - ARCA card: 10278/12654
2005 Journal Article CANOVESE L; VISENTIN F; CHESSA G.; SANTO C; UGUAGLIATI P Novel hetero-polymetallic derivatives of palladium bearing pyridylthioether fragments incorporating a Fe2(CO)6 cluster core as ligand in INORGANIC CHEMISTRY COMMUNICATIONS, vol. 8, pp. 1120-1124 (ISSN 1387-7003)
DOI - ARCA card: 10278/12362
2005 Journal Article CHESSA G.; CANOVESE L.; VISENTIN F.; SANTO C.; SERAGLIA R. Synthesis of poly(pyridylthioether) dendrimers incorporating a Fe2(CO)6 cluster core in TETRAHEDRON, vol. 61, pp. 1755-1763 (ISSN 0040-4020)
DOI - ARCA card: 10278/12653
2004 Journal Article BOLLETTA F.; GARELLI A.; MONTALTI M.; PRODI L.; ROMANO S.; ZACCHERONI N.; CANOVESE L.; CHESSA G.; SANTO C.; VISENTIN F. Synthesis, photophysical characterisation and metal ion binding properties of new ligands containing anthracene chromophores in INORGANICA CHIMICA ACTA, vol. 357, pp. 4078-4084 (ISSN 0020-1693)
DOI - ARCA card: 10278/12652
2003 Journal Article CANOVESE L; VISENTIN F; CHESSA G.; UGUAGLIATI P; SANTO C.; BANDOLI G.; MAINI L. Chloride-Modulated Insertion Reactions of Dimethylallene across the Pd-C Bond in Palladium Methyl Complexes Bearing Potentially Terdentate Pyridylthioether Ligands in ORGANOMETALLICS, vol. 22, pp. 3230-3238 (ISSN 0276-7333)
- ARCA card: 10278/12316
2003 Journal Article CANOVESE L; CHESSA G.; SANTO C.; VISENTIN F; UGUAGLIATI P Insertion of 1,1-Me2propadiene across the Pd–C bond of pyridyl–thioether methyl complexes. A mechanistic study in INORGANICA CHIMICA ACTA, vol. 346, pp. 158-168 (ISSN 0020-1693)
- ARCA card: 10278/12315
2002 Journal Article L. CANOVESE; V. LUCCHINI; C. SANTO; F. VISENTIN; A. ZAMBON A Novel Mechanism for the Fluxional Behaviour of [Pd(η2-tetramethylethylenetetracarboxylate)(2-methylthiomethylpyridine)] in JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 642, pp. 58-63 (ISSN 0022-328X)
- ARCA card: 10278/11333
2001 Journal Article CANOVESE L; VISENTIN F; SANTO C; CHESSA G.; UGUAGLIATI P Mechanism of the reaction of allyl amination of Pd(II) allyl complexes containing chelating pyridine chalcogen ligands. A surprisingly low influence of chalcogen atom in POLYHEDRON, vol. 20, pp. 3171-3181 (ISSN 0277-5387)
- ARCA card: 10278/12361

List of selected publications